Oxidative Cleavage of Diverse Ethers by an Extracellular Fungal Peroxygenase
نویسندگان
چکیده
منابع مشابه
Oxidative cleavage of allyl ethers by an oxoammonium salt.
A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.
متن کاملCLEAVAGE OF ESTERS AND ETHERS WITH SILICA CHLORIDE
Silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. It also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol
متن کاملOn the mechanism of oxidative cleavage of aryl-alkyl ethers by liver microsomes.
M. J. WARING. The Effects of Antimicrobial Agents on Ribonucleic Acid Polymerase 1 PHILIP REYES AND CHARLES HEIDELBERGER. Fluorinated Pyrimidines. XXVI. Mammalian Thymidylate Synthetase: Its Mechanism of Action and Inhibition by Fluorinated Nucleotides 14 DORA B. GOLDSTEIN. Effects of Barbital on Amino Acid Metabolism in Escherichia coli 31 CHOH HAO Li AND GUNNAR SAMUELSSON. Human Pituitary Gro...
متن کاملFatty Acid Chain Shortening by a Fungal Peroxygenase
A recently discovered peroxygenase from the fungus Marasmius rotula (MroUPO) is able to catalyze the progressive one-carbon shortening of medium and long-chain mono- and dicarboxylic acids by itself alone, in the presence of H2 O2 . The mechanism, analyzed using H218 O2 , starts with an α-oxidation catalyzed by MroUPO generating an α-hydroxy acid, which is further oxidized by the enzyme to a re...
متن کاملcleavage of esters and ethers with silica chloride
silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. it also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 2009
ISSN: 0021-9258
DOI: 10.1074/jbc.m109.040857